Issue 1, 2024

The interface-mediated electron structure tuning of RuOx–Co3O4 nano-particles for efficient electrocatalytic nitrate reduction

Abstract

The energy-intensive processes for the industrial production of ammonia necessitates the development of new methods to be proposed that will aid in reducing the global energy consumption. Specifically, the electrocatalytic nitrate reduction reaction (NO3RR) to produce ammonia is more thermodynamically feasible than the electrocatalytic nitrogen reduction reaction (NRR). However, it is hindered by a low catalytic activity due to its complex reaction pathways. Herein, we synthesized a novel electrocatalyst, RuOx–Co3O4 nanoparticles, with abundant interfaces, which exhibited an enhanced catalytic activity for efficient ammonia synthesis. This catalyst delivered a partial current density of 65.8 mA cm−2 for NH3 production, a faradaic efficiency (FE) of 89.7%, and a superior ammonia yield rate of up to 210.5 μmol h−1 cm−2 at −0.6 V vs. RHE. X-ray photoelectron and Raman spectroscopy revealed that the formed interfacial Ru–O–Co bond can decorate the electronic structures of the active sites and accelerate the absorption of NO3, thus promoting the production of ammonia.

Graphical abstract: The interface-mediated electron structure tuning of RuOx–Co3O4 nano-particles for efficient electrocatalytic nitrate reduction

Supplementary files

Article information

Article type
Paper
Submitted
09 Oct 2023
Accepted
16 Nov 2023
First published
17 Nov 2023

Dalton Trans., 2024,53, 162-170

The interface-mediated electron structure tuning of RuOx–Co3O4 nano-particles for efficient electrocatalytic nitrate reduction

Y. Liu, X. Jiang, Y. Zhang, H. Li, W. Huang, Y. Yang, M. Ye and Y. Liu, Dalton Trans., 2024, 53, 162 DOI: 10.1039/D3DT03318J

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