Issue 3, 2024

Bulky olefin epoxidation under mild conditions over Mo-based oxide catalysts

Abstract

Molybdenum-based epoxidation catalysts are among the most investigated since the homogeneous Mo-based catalytic process claimed by Halcon International Inc. for liquid phase olefin epoxidation (EPO). While homogeneous Mo-based catalytic technologies reached industrial implementation for olefin EPO, the same does not apply for heterogeneous Mo-based ones, which have not reached industrial implementation (e.g., to meet catalyst productivity and stability requirements). In this work, EPO nanocatalysts consisting of oxides possessing molybdenum and M = Ta, Nb or W were prepared via a simple, versatile methodology. The influence of the material synthesis conditions on the material properties was investigated to meet superior catalytic performances. Promising Mo-based solid catalysts were obtained which promoted the EPO of relatively bulky olefins such as fatty acid methyl esters (methyl oleate, methyl linoleate), using tert-butyl hydroperoxide as oxidant under mild conditions; e.g., the materials Mo(75D)M-0.3 with M = Nb, W (75 at% Mo relative to M, and MoO2Cl2 as precursor), obtained in a fast synthesis of 0.3 h, led to 92–96% epoxide selectivity at 84–95% methyl oleate conversion, at 70 °C. To the best of our knowledge, these are the first Mo,M oxides reported for these reactions.

Graphical abstract: Bulky olefin epoxidation under mild conditions over Mo-based oxide catalysts

Supplementary files

Article information

Article type
Paper
Submitted
17 Sep 2023
Accepted
01 Jan 2024
First published
02 Jan 2024
This article is Open Access
Creative Commons BY-NC license

Catal. Sci. Technol., 2024,14, 646-659

Bulky olefin epoxidation under mild conditions over Mo-based oxide catalysts

D. M. Gomes, X. Yao, P. Neves, N. Pinna, P. A. Russo and A. A. Valente, Catal. Sci. Technol., 2024, 14, 646 DOI: 10.1039/D3CY01299A

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