Issue 12, 2024

Defect-enabling zirconium-based metal–organic frameworks for energy and environmental remediation applications

Abstract

This comprehensive review explores the diverse applications of defective zirconium-based metal–organic frameworks (Zr-MOFs) in energy and environmental remediation. Zr-MOFs have gained significant attention due to their unique properties, and deliberate introduction of defects further enhances their functionality. The review encompasses several areas where defective Zr-MOFs exhibit promise, including environmental remediation, detoxification of chemical warfare agents, photocatalytic energy conversions, and electrochemical applications. Defects play a pivotal role by creating open sites within the framework, facilitating effective adsorption and remediation of pollutants. They also contribute to the catalytic activity of Zr-MOFs, enabling efficient energy conversion processes such as hydrogen production and CO2 reduction. The review underscores the importance of defect manipulation, including control over their distribution and type, to optimize the performance of Zr-MOFs. Through tailored defect engineering and precise selection of functional groups, researchers can enhance the selectivity and efficiency of Zr-MOFs for specific applications. Additionally, pore size manipulation influences the adsorption capacity and transport properties of Zr-MOFs, further expanding their potential in environmental remediation and energy conversion. Defective Zr-MOFs exhibit remarkable stability and synthetic versatility, making them suitable for diverse environmental conditions and allowing for the introduction of missing linkers, cluster defects, or post-synthetic modifications to precisely tailor their properties. Overall, this review highlights the promising prospects of defective Zr-MOFs in addressing energy and environmental challenges, positioning them as versatile tools for sustainable solutions and paving the way for advancements in various sectors toward a cleaner and more sustainable future.

Graphical abstract: Defect-enabling zirconium-based metal–organic frameworks for energy and environmental remediation applications

Associated articles

Article information

Article type
Review Article
Submitted
03 Feb 2024
First published
14 May 2024
This article is Open Access
Creative Commons BY license

Chem. Soc. Rev., 2024,53, 6244-6294

Defect-enabling zirconium-based metal–organic frameworks for energy and environmental remediation applications

S. Daliran, A. R. Oveisi, C. Kung, U. Sen, A. Dhakshinamoorthy, C. Chuang, M. Khajeh, M. Erkartal and J. T. Hupp, Chem. Soc. Rev., 2024, 53, 6244 DOI: 10.1039/D3CS01057K

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