Strong light–matter interaction and non-linear effects in organic semiconducting CuPc nanotubes: realization of all-optical diode and switching applications

Abstract

Spatial self-phase modulation based on the optical Kerr effect has gained momentum in recent years to analyse the nonlinear optical properties of 2D inorganic nanomaterials. In the present work, we investigate the strong light–matter interaction of organic semiconducting materials based on SSPM, by developing Cu-phthalocyanine (CuPc) nanotubes via a solvothermal technique. The low bandgap of CuPc facilitates the study of its nonlinear optical properties for a broad spectrum range from 671 nm to 405 nm. Intense laser light passing through the CuPc dispersion produces concentric diffraction ring patterns at the far field from which high n₂ and χ⁽³⁾ values, 3.667 × 10⁻⁵ cm² W⁻¹ and 2 × 10⁻³ esu, respectively, are obtained for the 405 nm laser. This strong nonlinear optical response of CuPc has been utilized to realize non-reciprocal light propagation by constructing a CuPc/SnS₂ hybrid structure, which makes an effective all-optical photonic diode. In addition, the all-optical switching is presented using CuPc nanotubes based on the spatial cross-phase modulation technique. In this technique a phase change is induced in the weak signal beam modulated by the strong controlling light beam, which helps to produce all-optical logic gates and all-optical switching devices. The experimental findings of this work unravel the potentially powerful applications of CuPc nanotubes in all-optical information transmission and all-optical photonic devices.