Issue 22, 2024

Computational prediction of the critical micelle concentration (CMC) of surfactants using the non-Bornian solvation model

Abstract

The non-Bornian solvation model was used to predict the Gibbs energy change for the adsorption–desorption processes of ionic (14 anionic and 9 cationic) surfactants and 19 non-ionic surfactants at the interface between oil (O) (=nitrobenzene) and water (W). Except for 10 non-ionic surfactants (polyoxyethylenes) having semi-hydrophobic –OC2H4– groups, both ionic and non-ionic surfactants showed a clear energy minimum in their adsorption–desorption processes, providing reliable values of Gibbs energies, Image ID:d4cp00714j-t1.gif and Image ID:d4cp00714j-t2.gif, for the two adsorption processes from their respective bulk phases to the interface (I). It was then found that the critical micelle concentration (CMC) for surfactants (especially for the ionic ones) is linearly related to the two independent variables, i.e., Image ID:d4cp00714j-t3.gif and Image ID:d4cp00714j-t4.gif.

Graphical abstract: Computational prediction of the critical micelle concentration (CMC) of surfactants using the non-Bornian solvation model

Supplementary files

Article information

Article type
Paper
Submitted
19 Feb 2024
Accepted
09 May 2024
First published
10 May 2024

Phys. Chem. Chem. Phys., 2024,26, 16320-16326

Computational prediction of the critical micelle concentration (CMC) of surfactants using the non-Bornian solvation model

T. Osakai, T. Misaki and K. Eda, Phys. Chem. Chem. Phys., 2024, 26, 16320 DOI: 10.1039/D4CP00714J

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