Issue 13, 2024

Synthesis of an iron-based metal–organic framework with octahedral cages for the selective capture of sulfur hexafluoride

Abstract

The assembly of a metal–organic framework (MOF) containing bent phenanthroline linkers and iron trinuclear clusters remains rare. Herein, we report the synthesis and single crystal structure of a two-dimensional (2D) MOF, Fe-cage-MOF, assembled from 2,9-substituted phenanthroline based carboxylate linkers and pre-synthesized iron trinuclear clusters. The distinctive octahedral cages and ordered 1D channels endow the MOF with permanent porosity and potential for selective capture of the greenhouse gas sulfur hexafluoride.

Graphical abstract: Synthesis of an iron-based metal–organic framework with octahedral cages for the selective capture of sulfur hexafluoride

Supplementary files

Article information

Article type
Paper
Submitted
16 Jan 2024
Accepted
23 Feb 2024
First published
23 Feb 2024

CrystEngComm, 2024,26, 1912-1916

Synthesis of an iron-based metal–organic framework with octahedral cages for the selective capture of sulfur hexafluoride

H. Wang, L. Shi, H. Cao, Z. Xiong, S. Ma, J. Pan and Z. Chen, CrystEngComm, 2024, 26, 1912 DOI: 10.1039/D4CE00041B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements