Tartaric acid-derived chiral carbon nanodots for catalytic enantioselective ring-opening reactions of styrene oxide

Xinyi Zhao; Yana Reva; Bikash Jana; Daniel Langford; Marina Kinzelmann; Zhipeng Zhang; Qi Liu; Thomas Drewello; Dirk M. Guldi; Xiaoqing Chen

doi:10.1039/D4CC04119D

Tartaric acid-derived chiral carbon nanodots for catalytic enantioselective ring-opening reactions of styrene oxide†

Xinyi Zhao,^a Yana Reva,^b Bikash Jana,^bd Daniel Langford,

^b Marina Kinzelmann,^e Zhipeng Zhang,^a Qi Liu,

*^a Thomas Drewello,

^e Dirk M. Guldi

*^b and Xiaoqing Chen

*^ac

Author affiliations

* Corresponding authors

^a College of Chemistry and Chemical Engineering, Central South University, Changsha, China
E-mail: iliuqi@csu.edu.cn, xqchen@csu.edu.cn

^b Department of Chemistry and Pharmacy & Interdisciplinary Center for Molecular Materials (ICMM), Physical Chemistry I, Friedrich-Alexander-Universität Erlangen-Nürnberg, Erlangen, Germany
E-mail: dirk.guldi@fau.de

^c Key Laboratory of Hunan Province for Water Environment and Agriculture Product Safety, Central South University, Changsha 410083, China

^d Schulich Faculty of Chemistry, Israel Institute of Technology, Technion, Israel

^e Department of Chemistry and Pharmacy, Physical Chemistry I, Friedrich-Alexander-Universität Erlangen-Nürnberg, Erlangen, Germany

Abstract

Chiral carbon nanodots (CNDs) were fabricated through the hydrothermal processing of sulfanilic acid and chiral tartaric acid, exhibiting outstanding catalytic performance for the chiral catalysis of the ring-opening reaction. Furthermore, the catalytic mechanism was proposed to understand the link between the chiral structure and the performance of the catalyst.

Chemical Communications

Tartaric acid-derived chiral carbon nanodots for catalytic enantioselective ring-opening reactions of styrene oxide†

Abstract

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Tartaric acid-derived chiral carbon nanodots for catalytic enantioselective ring-opening reactions of styrene oxide

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