Issue 76, 2024

Synthesis and characterization of chlorotriarylbismuthonium salts

Abstract

This work reports the synthesis and structural study of a family of chlorotriarylbismuthonium salts. The abstraction of a chlorine atom with NaBArF from triarylbismuth dichloride species leads to monomeric and dimeric chlorotriarylbismuthonium species, which show a distinct behavior in solution and solid-state in comparison to their fluorotriarylbismuthonium analogues.

Graphical abstract: Synthesis and characterization of chlorotriarylbismuthonium salts

Supplementary files

Article information

Article type
Communication
Submitted
08 Jul 2024
Accepted
25 Aug 2024
First published
27 Aug 2024
This article is Open Access
Creative Commons BY license

Chem. Commun., 2024,60, 10532-10535

Synthesis and characterization of chlorotriarylbismuthonium salts

J. Kuziola, N. Nöthling, M. Leutzsch and J. Cornella, Chem. Commun., 2024, 60, 10532 DOI: 10.1039/D4CC03364G

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements