Issue 75, 2024
From the journal:

Chemical Communications

Twisted diphenoquinones fused with thiophene rings: thiophene analogs of bianthrone†

Yohei Adachi, ORCID logo *a   Yuto Hattori,a   Tsubasa Mikie, ORCID logo b   Itaru Osaka ORCID logo b  and  Joji Ohshita ORCID logo *ac  

* Corresponding authors

a Smart Innovation Program, Graduate School of Advanced Science and Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan
E-mail: yadachi@hiroshima-u.ac.jp, jo@hiroshima-u.ac.jp

b Applied Chemistry Program, Graduate School of Advanced Science and Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan

c Division of Materials Model-Based Research, Digital Monozukuri (Manufacturing) Education and Research Center, Hiroshima University, 3-10-32 Kagamiyama, Higashi-Hiroshima, Hiroshima 739-0046, Japan

Abstract

The twisted conformer of bistricyclic aromatic enes (BAEs) has a small HOMO–LUMO gap owing to the twisted double bond. In this study, we synthesized diphenoquinones fused with thiophene rings as a new twisted conformer-predominant BAE. They exhibited deep LUMO energy levels and apparent n-type semiconductor properties.

Graphical abstract: Twisted diphenoquinones fused with thiophene rings: thiophene analogs of bianthrone

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Article information

DOI
https://doi.org/10.1039/D4CC02943G
Article type
Communication
Submitted
18 Jun 2024
Accepted
22 Aug 2024
First published
23 Aug 2024
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2024,60, 10410-10413

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Twisted diphenoquinones fused with thiophene rings: thiophene analogs of bianthrone

Y. Adachi, Y. Hattori, T. Mikie, I. Osaka and J. Ohshita, Chem. Commun., 2024, 60, 10410 DOI: 10.1039/D4CC02943G

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