Issue 73, 2024

Topochemically synthesized Nb3VS6 as a stable anode for sodium-ion batteries

Abstract

Ternary metal sulfides having layered morphology are considered as potential active materials for various applications. Herein, Nb3VS6 is synthesized topochemically for the first time using a Nb–V–HDA complex having a lamellar structure by employing H2S gas as the sulfidation agent. Nb3VS6, as an anode for SIBs, exhibited a specific capacity of 101.15 mA h g−1 at 0.5 A g−1, along with excellent cycling stability with 100% capacity retention after 2500 cycles.

Graphical abstract: Topochemically synthesized Nb3VS6 as a stable anode for sodium-ion batteries

Supplementary files

Article information

Article type
Communication
Submitted
30 May 2024
Accepted
14 Aug 2024
First published
23 Aug 2024

Chem. Commun., 2024,60, 10017-10020

Topochemically synthesized Nb3VS6 as a stable anode for sodium-ion batteries

H. Pandey, P. Chithaiah, S. Vishwanathan, H. S. S. Ramakrishna Matte and C. N. R. Rao, Chem. Commun., 2024, 60, 10017 DOI: 10.1039/D4CC02630F

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