Issue 72, 2024

Tetraphenylpentalenide organolanthanide complexes

Abstract

The D2h symmetrical 1,3,4,6-tetraphenylpentalenide is an excellent ligand for the stabilisation of strongly coloured bis(pentalenide) LnIII sandwich complexes. These easily accessible compounds complement previously reported lanthanide organometallics and provide new opportunities to understand the roles of the f-orbitals in electronic structure and bonding.

Graphical abstract: Tetraphenylpentalenide organolanthanide complexes

Supplementary files

Article information

Article type
Communication
Submitted
27 May 2024
Accepted
08 Jul 2024
First published
12 Jul 2024
This article is Open Access
Creative Commons BY license

Chem. Commun., 2024,60, 9749-9752

Tetraphenylpentalenide organolanthanide complexes

N. J. Katzer, M. Kaur, A. Sen, R. Nimaiyar, J. Autschbach, P. L. Arnold and U. Hintermair, Chem. Commun., 2024, 60, 9749 DOI: 10.1039/D4CC02570A

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements