Issue 61, 2024

Amplification of negative gas adsorption in a multivariate framework

Abstract

The approach of employing multivariate MOFs was used to fine-tune the mechanical properties of the flexible framework DUT-49. In situ XRD, NMR and physisorption studies showed that the partial incorporation of a more rigid linker into the DUT-49 framework enables stabilization of the metastable open pore phase, which led to a two-fold amplification of the expelled gas amount upon the “negative gas adsorption” transition.

Graphical abstract: Amplification of negative gas adsorption in a multivariate framework

Supplementary files

Article information

Article type
Communication
Submitted
24 May 2024
Accepted
20 Jun 2024
First published
21 Jun 2024

Chem. Commun., 2024,60, 7886-7889

Amplification of negative gas adsorption in a multivariate framework

F. Walenszus, V. Bon, A. De and S. Kaskel, Chem. Commun., 2024, 60, 7886 DOI: 10.1039/D4CC02540G

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