Issue 68, 2024

Coordination-induced reductive elimination from a titanium(iv) complex

Abstract

Diamidopyridine-supported titanium dibenzyl complexes undergo coordination-induced C–C reductive elimination upon addition of alkynes and quantitative formation of titanacyclopentadienes. The distinct radical mechanism of this reductive mechanism gives new insights into C–C bond formation with titanium.

Graphical abstract: Coordination-induced reductive elimination from a titanium(iv) complex

Supplementary files

Article information

Article type
Communication
Submitted
23 May 2024
Accepted
14 Jul 2024
First published
15 Jul 2024

Chem. Commun., 2024,60, 9030-9033

Coordination-induced reductive elimination from a titanium(IV) complex

P. Fritsche, L. Geyer, C. Czernetzki and G. Hierlmeier, Chem. Commun., 2024, 60, 9030 DOI: 10.1039/D4CC02500H

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