Issue 65, 2024

A neutral crystalline imino-substituted silyl radical

Abstract

The neutral three-coordinated imino(silyl)silyl radical was isolated from the reaction of N-heterocyclic iminosilicon tribromide (ItBuN-SiBr3) with NaSitBu2Me. The radical was fully characterized by X-ray crystallography and electron paramagnetic resonance spectroscopy and supported by quantum chemical calculations.

Graphical abstract: A neutral crystalline imino-substituted silyl radical

Supplementary files

Article information

Article type
Communication
Submitted
04 May 2024
Accepted
09 Jul 2024
First published
10 Jul 2024
This article is Open Access
Creative Commons BY license

Chem. Commun., 2024,60, 8577-8580

A neutral crystalline imino-substituted silyl radical

F. J. Kiefer, A. Kostenko, R. Holzner and S. Inoue, Chem. Commun., 2024, 60, 8577 DOI: 10.1039/D4CC02167C

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