Issue 60, 2024

Chemical shaping of CPO-27-M (M = Co, Ni) through an in situ crystallization within chitosan hydrogels

Abstract

The preparation of MOF composites is considered as an effective method to address the challenges of shaping MOFs and to create porous solids with enhanced properties and broader applications. In this study, CPO-27-Co was crystallized via a simple strategy within porous chitosan beads. The resulting CS@CPO-27-Co composites were tested for CO2 sorption and they demonstrated promising performances by exceeding 3 mmol(CO2) g−1. The versatility of this strategy was further demonstrated by replacing cobalt(II) ions with nickel(II), also leading to the isostructural CPO-27 framework.

Graphical abstract: Chemical shaping of CPO-27-M (M = Co, Ni) through an in situ crystallization within chitosan hydrogels

Supplementary files

Article information

Article type
Communication
Submitted
30 Apr 2024
Accepted
01 Jul 2024
First published
01 Jul 2024
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2024,60, 7717-7720

Chemical shaping of CPO-27-M (M = Co, Ni) through an in situ crystallization within chitosan hydrogels

Y. Khadiri, C. Volkringer, S. Royer, A. El Kadib, T. Loiseau and J. Dhainaut, Chem. Commun., 2024, 60, 7717 DOI: 10.1039/D4CC02082K

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