Issue 66, 2024

In situ confinement of ultra-small metal nanoparticles in redox-active zirconium MOFs for catalysis

Abstract

Herein, we successfully fabricated ultra-small metal nanoparticles into two stable Zr-based metal–organic frameworks via in situ redox reactions between triphenylamine and the corresponding metal ions to afford Pd NPs@1 and Pd NPs@2, which exhibit excellent activity and reusability for Suzuki coupling reactions as heterogeneous catalysts.

Graphical abstract: In situ confinement of ultra-small metal nanoparticles in redox-active zirconium MOFs for catalysis

Supplementary files

Article information

Article type
Communication
Submitted
25 Apr 2024
Accepted
18 Jul 2024
First published
18 Jul 2024

Chem. Commun., 2024,60, 8708-8711

In situ confinement of ultra-small metal nanoparticles in redox-active zirconium MOFs for catalysis

F. Li, J. Huang, Y. Meng, J. Li, L. Zhang and D. Sheng, Chem. Commun., 2024, 60, 8708 DOI: 10.1039/D4CC01976H

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