Reduction of (pddi)Cr reveals redox noninnocence via C–C bond formation amidst competing electrophilicity: [(cpta)CrMen]− (n = 0, 1) and [(pta)Cr]−

Abstract

Reversible cyclopropane formation is probed as a means of redox noninnocence in diimine/diamide chelates via reduction and complex anion formation. Competition from imine attack renders complications in the latter approach, and electrochemical measurements with calculational support provide the rationale.