Surface modified copper foam with cobalt phthalocyanine carbon nanotube hybrids for tuning CO2 reduction reaction products

Javier O. Rivera-Reyes; Keith J. Billings; Carmen L. Metzler; Richard M. Lagle; Mebougna Drabo; Ratnakar Palai; John-Paul Jones; Dalice M. Piñero Cruz

doi:10.1039/D4CC00715H

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Surface modified copper foam with cobalt phthalocyanine carbon nanotube hybrids for tuning CO₂ reduction reaction products†

Javier O. Rivera-Reyes,^ab Keith J. Billings,^c Carmen L. Metzler,^ab Richard M. Lagle,^d Mebougna Drabo,^d Ratnakar Palai,^e John-Paul Jones^c and Dalice M. Piñero Cruz

*^ab

Author affiliations

* Corresponding authors

^a Chemistry Department, College of Natural Sciences, Rio Piedras Campus, University of Puerto Rico, San Juan, PR 00931-3346, USA
E-mail: dalice.pinero@upr.edu

^b Molecular Science Research Center, University of Puerto Rico, 1390 Ponce de León, San Juan, PR 00926, USA

^c Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109, USA

^d Department of Mechanical Engineering, Alabama A&M University, Huntsville, Alabama 35762, USA

^e Department of Physics, College of Natural Sciences, Rio Piedras Campus, University of Puerto Rico, San Juan, PR, USA

Abstract

The CO₂ reduction reaction (CO₂RR) is a feasible way to convert this greenhouse gas into molecules of industrial interest. Herein we present the modification of the Cu foam cathode using molecular catalyst hybrid from cobalt phthalocyanine (CoPc) to increase selectivity and stability towards CO₂RR products in a flow cell setup.

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Article information

DOI: https://doi.org/10.1039/D4CC00715H
Article type: Communication
Submitted: 13 Feb 2024
Accepted: 31 Mar 2024
First published: 15 Apr 2024
This article is Open Access

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Chem. Commun., 2024,60, 4850-4853

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Surface modified copper foam with cobalt phthalocyanine carbon nanotube hybrids for tuning CO₂ reduction reaction products

J. O. Rivera-Reyes, K. J. Billings, C. L. Metzler, R. M. Lagle, M. Drabo, R. Palai, J. Jones and D. M. Piñero Cruz, Chem. Commun., 2024, 60, 4850 DOI: 10.1039/D4CC00715H

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