Issue 17, 2024

Circularly polarized phosphorescence with a large dissymmetry factor from a helical platinum(ii) complex

Abstract

A chiral platinum(II) complex with a helical Schiff-base [4]helicene ligand exhibits intense red circularly polarized phosphorescence (CPP) with a glum of 0.010 in the dilute solution state. The intense CPP was caused by a change in the electronic transition character based on the induction of the helical structure.

Graphical abstract: Circularly polarized phosphorescence with a large dissymmetry factor from a helical platinum(ii) complex

Supplementary files

Article information

Article type
Communication
Submitted
27 Dec 2023
Accepted
27 Jan 2024
First published
30 Jan 2024

Chem. Commun., 2024,60, 2413-2416

Circularly polarized phosphorescence with a large dissymmetry factor from a helical platinum(II) complex

M. Ikeshita, S. Watanabe, S. Suzuki, S. Tanaka, S. Hattori, K. Shinozaki, Y. Imai and T. Tsuno, Chem. Commun., 2024, 60, 2413 DOI: 10.1039/D3CC06293G

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