Sustainable release of LiNO3 in carbonate electrolytes for stable lithium metal anodes

Abstract

LiNO₃ is recognized as an effective additive, forming a dense, nitrogen-rich solid electrolyte interphase (SEI) on lithium's surface, which safeguards it from parasitic reactions. However, its use is limited due to the poor solubility in carbonate electrolytes. Herein, we introduce a bilayer separator designed to release LiNO₃ sustainably. This continual release not only alters the chemistry of the SEI but also replenishes the additives that are depleted during battery cycling, thereby enhancing the durability of the modified interphase. This strategy effectively curtails Li dendrite formation, significantly enhancing the longevity of Li|LiFePO₄ batteries, evidenced by an impressive 85% capacity retention after 800 cycles. This research offers a compelling remedy to the longstanding challenge of incorporating LiNO₃ in carbonate electrolytes.