Issue 24, 2024

Ligand engineering to achieve synergistic properties in a 2D bilayer supertetrahedral chalcogenide cluster-based assembled material

Abstract

Incorporating functional organic linkers into supertetrahedral chalcogenolate cluster-based materials is an effective synthetic strategy to expand structural diversity and generate tunable optical and photoelectric properties arising from synergistic effects. Herein, a mixed ligand engineering approach was adopted to design a supertetrahedral cluster-based assembled material [(Cd6Ag4(SPh)16(TPPA)(BPE)0.5)·2DMF]n (denoted as SCCAM-3) with a 2D bilayer architecture and broader visible-light absorption. Interestingly, SCCAM-3 demonstrates a long-lived afterglow at 83 K and efficient photocatalytic activity for degrading tetracycline in water.

Graphical abstract: Ligand engineering to achieve synergistic properties in a 2D bilayer supertetrahedral chalcogenide cluster-based assembled material

Supplementary files

Article information

Article type
Communication
Submitted
22 Nov 2023
Accepted
22 Feb 2024
First published
23 Feb 2024

Chem. Commun., 2024,60, 3279-3282

Ligand engineering to achieve synergistic properties in a 2D bilayer supertetrahedral chalcogenide cluster-based assembled material

Y. Li, Y. Liu, W. Li, F. Li, Y. Feng, X. Luo and Y. Han, Chem. Commun., 2024, 60, 3279 DOI: 10.1039/D3CC05726G

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