Microwave-assisted synthesis of Co-free Li[Li0.2Ni0.2Mn0.6]O2 cathodes with a spinel-layered coherent structure for high-power Li-ion batteries

Abstract

Li- and Mn-rich layered oxides (LMLOs) are regarded as the most promising cathode materials for Li-ion batteries (LIBs), but they suffer from poor rate capability. Herein, a promising and practical method (i.e. a hydroxide coprecipitation method in combination with a microwave heating process) is developed to controllably synthesize cobalt-free Li[Li_0.2Ni_0.2Mn_0.6]O₂ with a layered/spinel heterostructure (LLNMO-LS). The cathode made of the LLNMO-LS delivers an excellent electrochemical performance, demonstrating a discharge capacity of 147 mA h g⁻¹ at 10C.