Issue 12, 2023

Efficient procedure for biodiesel synthesis from waste oil and t-butylation of resorcinol using a porous microtube polymer-based solid acid

Abstract

A novel porous microtube polymer-based solid acid was synthesized via the polymerisation of naphthalene and subsequent sulfonation. The polymer structure could be easily adjusted by altering the amount of formaldehyde dimethyl acetal (FDA), and could be changed to thin slices, microtubes or microspheres. The high surface area of 128.92 m2 g−1 and special microtube structure indicated good mass transfer efficiency and a hydrophobic surface. The abundant naphthalene rings provided sufficient sulfonation sites, which resulted in a high acid density of over 3 mmol g−1. An efficient procedure for biodiesel synthesis and t-butylation of resorcinol were developed using the novel solid acid. The high Brunauer–Emmett–Teller (BET) surface area, special microtube structure and organic framework were the key factors for the high activities, providing great potential in green chemistry.

Graphical abstract: Efficient procedure for biodiesel synthesis from waste oil and t-butylation of resorcinol using a porous microtube polymer-based solid acid

Article information

Article type
Paper
Submitted
13 Aug 2023
Accepted
12 Oct 2023
First published
18 Oct 2023
This article is Open Access
Creative Commons BY-NC license

Energy Adv., 2023,2, 2140-2149

Efficient procedure for biodiesel synthesis from waste oil and t-butylation of resorcinol using a porous microtube polymer-based solid acid

Z. Guo and X. Liang, Energy Adv., 2023, 2, 2140 DOI: 10.1039/D3YA00394A

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