Issue 34, 2023

Effect of channel thickness on radiation hardness of solution-processed oxide thin film transistors

Abstract

The effect of channel thickness on the radiation hardness of solution-processed amorphous zinc–indium–tin–oxide (a-ZITO) thin film transistors (TFTs) with a Zn : In : Sn ratio of 4 : 1 : 1 has been investigated. Proton ex situ device measurements and XPS analysis showed that oxide TFTs with smaller channel thickness exhibited greater radiation tolerance. Furthermore, from the energy bandgap and conduction band offset calculations, it was confirmed that a-ZITO TFTs with a thinner channel reduced the doping of electrons from shallow donor states to the conduction band minimum against proton irradiation. For in situ measurements of device characteristics during proton irradiation with electrical stress, a significant degradation was observed due to the generation of oxygen vacancies within the semiconductor lattice and localized traps by proton-induced electron–hole pairs in the gate dielectric. As a result, the thinnest a-ZITO TFT (4 nm channel thickness) exhibited the most stable electrical performance with ΔVth of −10.7 V and −0.5 V, and Δμ of 4.0 cm2 V−1 s−1 and 0.1 cm2 V−1 s−1 during in situ and ex situ measurements, respectively. This study provided a relatively detailed analysis in real-time, compared to the present state of the art, and suggested the effect of channel thickness on radiation hardness.

Graphical abstract: Effect of channel thickness on radiation hardness of solution-processed oxide thin film transistors

Supplementary files

Article information

Article type
Paper
Submitted
28 Jun 2023
Accepted
27 Jul 2023
First published
27 Jul 2023

J. Mater. Chem. C, 2023,11, 11542-11551

Effect of channel thickness on radiation hardness of solution-processed oxide thin film transistors

H. Kang, D. Ho, Y. Kim, J. Kim, H. Kim and C. Kim, J. Mater. Chem. C, 2023, 11, 11542 DOI: 10.1039/D3TC02267F

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