Issue 51, 2023, Issue in Progress

A tri(ethylene glycol)-tethered Morita–Baylis–Hillman dimer in the formation of macrocyclic crown ether-paracyclophane hybrid structures

Abstract

A Morita–Baylis–Hillman acetate was dimerized by a click-chemistry Copper(I)-Catalysed Azide–Alkyne Cycloaddition (CuAAC) reaction employing a tri(ethylene glycol) diazide derivative to obtain a dimeric MBHA derivative. The reaction of this dimeric MBHA derivative with n-butylamine afforded a photoisomerizable macrocyclic crown ether-paracyclophane hybrid architecture that is potentially useful in a large variety of applications as well as those already well-known for crown ethers.

Graphical abstract: A tri(ethylene glycol)-tethered Morita–Baylis–Hillman dimer in the formation of macrocyclic crown ether-paracyclophane hybrid structures

Supplementary files

Article information

Article type
Paper
Submitted
06 Oct 2023
Accepted
27 Nov 2023
First published
11 Dec 2023
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2023,13, 35773-35780

A tri(ethylene glycol)-tethered Morita–Baylis–Hillman dimer in the formation of macrocyclic crown ether-paracyclophane hybrid structures

M. Saletti, J. Venditti, M. Paolino, A. Zacchei, G. Giuliani, G. Giorgi, C. Bonechi, A. Donati and A. Cappelli, RSC Adv., 2023, 13, 35773 DOI: 10.1039/D3RA06792K

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