Recent advances on the methods developed for the identification and detection of emerging contaminant microplastics: a review

Abstract

The widespread use of plastics, popular for their versatility and cost-efficiency in mass production, has led to their essential role in modern society. Their remarkable attributes, such as flexibility, mechanical strength, lightweight, and affordability, have further strengthened their importance. However, the emergence of microplastics (MPs), minute plastic particles, has raised environmental concerns. Over the last decade, numerous studies have uncovered MPs of varying sizes in diverse environments. They primarily originate from textile fibres and cosmetic products, with large plastic items undergoing degradation and contributing as secondary sources. The bioaccumulation of MPs, with potential ingestion by humans through the food chain, underscores their significance as environmental contaminants. Therefore, continuous monitoring of environmental and food samples is imperative. A range of spectroscopic techniques, including vibrational spectroscopy, Raman spectroscopy, Fourier-transform infrared (FT-IR) spectroscopy, hyperspectral imaging, and nuclear magnetic resonance (NMR) spectroscopy, facilitates the detection of MPs. This review offers a comprehensive overview of the analytical methods employed for sample collection, characterization, and analysis of MPs. It also emphasizes the crucial criteria for selecting practical and standardized techniques for the detection of MPs. Despite advancements, challenges persist in this field, and this review suggests potential strategies to address these limitations. The development of effective protocols for the accurate identification and quantification of MPs in real-world samples is of paramount importance. This review further highlights the accumulation of microplastics in various edible species, such as crabs, pelagic fish, finfish, shellfish, American oysters, and mussels, shedding light on the extreme implications of MPs on our food chain.