Room temperature synthesis of CdSe/CdS triangular nanoemitters and their stabilization in colloidal state and sol–gel glass

Abstract

Heterostructured cadmium-based core–shell nanoparticles (NPs) are the subject of research because of not only fundamental scientific advances but also a range of technological applications. To increase the range of applications of nanoparticles, it is possible to immobilise them in sol–gel glass that can be easily manufactured and shaped, keeping the properties of the dispersed particles. This allows the creation of new bulk optical materials with tailored properties, opening up opportunities for various technological applications such as lighting or sensing. Herein we report the synthesis of core–shell CdSe/CdS triangular-shaped nanoparticles under an atmosphere of oxygen and at room temperature. A detailed characterisation of the obtained NPs was carried out. The interesting effect of the gelling agent (tetra-n-butylammonium fluoride) on the triangular nanoparticles in solution and the stability of the emission properties over time was investigated. Sol–gel glasses with entrapped triangular NPs were prepared, and their photoluminescence properties were compared with those obtained in colloidal solutions.