Superior mechanical, electrical, dielectric, and EMI shielding properties of ethylene propylene diene monomer (EPDM) based carbon black composites

Abstract

In this study, the mechanical, electrical, dielectric, and electromagnetic interference (EMI) shielding properties of ethylene propylene diene monomer (EPDM) based carbon black composites, namely high abrasion furnace (HAF) and conductive Printex blacks, were investigated and their effectiveness compared. The results show that Printex black filled composites exhibited superior properties in all aspects compared to HAF filled composites. The electrical percolation threshold value of Printex black filled composites was approximately 1/2 to 1/3 lower compared to HAF black filled composites based on classical theory and the Sigmoidal model. Moreover, the tensile modulus, dielectric permittivity, and EMI shielding efficiency (SE) of the Printex black filled composites were 4.6 times, in the order of 10⁶ at 1 kHz, and 6.65 times improved compared to HAF black filled composites at their 40 phr loadings, respectively. The Printex black filled 40 phr loaded composite showed an EMI SE of 49.94 dB that is 99.999% the attenuation of EM radiation. These properties can be attributed to the high structure of Printex black, which facilitates the ease of formation of the conductive channel through the polymer matrix, higher reinforcement, higher interfacial polarization, and high absorption of radiation. These properties were compared with some published literature on carbon black filled composites and it was found that the results of the Printex black filled composites are highly competitive with the published work. The results show that these composites are highly effective for load bearing materials, supercapacitors, and EM radiation protection.