The Mizoroki–Heck reaction between in situ generated alkenes and aryl halides: cross-coupling route to substituted olefins

Anushka Koranne; Shrishty Turakhia; Vikesh Kumar Jha; Sangeeta Gupta; Rangnath Ravi; Abhijeet Mishra; Anil K. Aggarwal; Chandan Kumar Jha; Neelu Dheer; Abadh Kishor Jha

doi:10.1039/D3RA03533F

The Mizoroki–Heck reaction between in situ generated alkenes and aryl halides: cross-coupling route to substituted olefins

Anushka Koranne,^a Shrishty Turakhia,^a Vikesh Kumar Jha,^b Sangeeta Gupta,^a Rangnath Ravi,^c Abhijeet Mishra,^c Anil K. Aggarwal,^c Chandan Kumar Jha,^d Neelu Dheer

^e and Abadh Kishor Jha

*^a

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* Corresponding authors

^a Govt. Shivnath Science College, Rajnandgaon, Chhattisgarh, India
E-mail: awadhbrave@gmail.com

^b Govt. R. R. M. PG College, Surajpur, Chhattisgarh, India

^c Shivaji College, University of Delhi, Delhi, India

^d Govt. Engineering College, Madhubani, Bihar, India

^e Acharya Narendra Dev College, University of Delhi, Delhi, India

Abstract

This review covers palladium-catalyzed typical Mizoroki–Heck cross-coupling reactions of aryl halides with in situ generated alkenes, by following a typical Heck coupling mechanism to form substituted olefins unlike direct cross-coupling of alkenes with aryl halides in Heck olefination. These reactions solve the issue of alkenes undergoing polymerization at high temperatures and increase reaction efficiency by reducing the reaction time and purification steps.

This article is part of the themed collection: 2023 Reviews in RSC Advances

RSC Advances

The Mizoroki–Heck reaction between in situ generated alkenes and aryl halides: cross-coupling route to substituted olefins

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The Mizoroki–Heck reaction between in situ generated alkenes and aryl halides: cross-coupling route to substituted olefins

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