Efficient oxidation of benzyl alcohol into benzaldehyde catalyzed by graphene oxide and reduced graphene oxide supported bimetallic Au–Sn catalysts

Abstract

A series of bimetallic and monometallic catalysts comprising Au and Sn nanoparticles loaded on graphene oxide (GO) and reduced graphene oxide (rGO) were prepared using three distinct techniques: two-step immobilization, co-immobilization, and immobilization. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), energy dispersive X-ray (EDX), and Inductively-coupled plasma optical emission spectroscopy (ICP-OES) were used to characterize the chemical and physical properties of prepared Au–Sn bimetallic and Au or Sn monometallic nanocatalysts. The catalytic performance of the prepared nanocatalysts was evaluated in the selective oxidation of benzyl alcohol (BzOH) to benzaldehyde (BzH) using O₂ as an oxidizing agent under moderate conditions. To obtain the optimal BzH yield, the experimental conditions and parameters, including the effects of the reaction time, temperature, pressure, and solvent type on BzOH oxidation, were optimized. Under optimal reaction conditions, bimetallic Au–Sn nanoparticles supported on GO (AuSn/GO-TS, 49.3%) produced a greater yield of BzH than the AuSn/rGO-TS catalysts (35.5%). The Au–Sn bimetallic catalysts were more active than the monometallic catalysts. AuSn/GO-TS and AuSn/rGO-TS prepared by the two-step immobilization method were more active than AuSn/GO-CoIM and AuSn/rGO-CoIM prepared by co-immobilization. In addition, the AuSn/GO-TS and AuSn/rGO-TS catalysts were easily separated from the mixture by centrifugation and reused at least four times without reducing the yield of BzH. These properties make Au–Sn bimetallic nanoparticles supported on GO and rGO particularly attractive for the environmentally friendly synthesis of benzaldehyde.