Phosphanyl-substituted tin(II) half sandwich complexes are reported. Due to the Lewis acidic tin center and Lewis basic phosphorous atom they form head-to-tail dimers. Their properties and reactivities were investigated both experimentally and theoretically. Furthermore, related transition metal complexes of these species are presented.
C. Müller, J. Schu, B. Morgenstern, M. Zimmer, M. Schmidtmann and A. Schäfer, RSC Adv., 2023, 13, 10249 DOI: 10.1039/D3RA01384G
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