Microporous carbon for fast and simple electrochemical detection of imidacloprid insecticide in fruit and water samples

Abstract

Herein, a fast and sensitive electrochemical sensor was developed for imidacloprid detection using low-cost disposable microporous carbon screen-printed electrodes. The electrochemical behaviour of imidacloprid at the microporous material was investigated in detail. The developed sensor allowed imidacloprid detection in the linear range of 0.00–1.00 mM with a sensitivity of 14.43 ± 0.42 μA mM⁻¹ and a detection limit of 2.54 μM (3s_B/m). The sensor showed excellent selectivity and high tolerance to possible interference from other tested insecticides and ions. Excellent repeatability (3.42%, n = 3) and reproducibility (2.23%, n = 3) were demonstrated. Application of the sensor in various fruit and water samples without any treatment showed 96.2–103.0% recoveries. The developed sensor further revealed that the most effective method for removing imidacloprid residue from fruit samples was via washing with a mixture of 5% w/v NaCl and 5% w/v bicarbonate at 40 °C.