Ultrasonic spray pyrolysis synthesis of TiO2/Al2O3 microspheres with enhanced removal efficiency towards toxic industrial dyes

Abstract

Developing low-cost and highly effective adsorbent materials to decolorate wastewater is still challenging in the industry. In this study, TiO₂-modified Al₂O₃ microspheres with different TiO₂ contents were produced by spray pyrolysis, which is rapid and easy to scale up. Results reveal that the modification of γ-Al₂O₃ with TiO₂ reduced the crystallite size of Al₂O₃ and generated more active sites in the composite sample. The as-synthesized Al₂O₃–TiO₂ microspheres were applied to remove anionic methyl orange (MO) and cationic rhodamine B (RB) dyes in an aqueous solution using batch and continuous flow column sorption processes. Results show that the Al₂O₃ microspheres modified with 15 wt% of TiO₂ exhibited the maximum adsorbing capacity of ∼41.15 mg g⁻¹ and ∼32.28 mg g⁻¹ for MO and RB, respectively, exceeding the bare γ-Al₂O₃ and TiO₂. The impact of environmental complexities on the material's reactivity for the organic pollutants was further delineated by adjusting the pH and adding coexisting ions. At pH ∼5.5, the TiO₂/Al₂O₃ microspheres showed higher sorption selectivity towards MO. In the continuous flow column removal, the TiO₂/Al₂O₃ microspheres achieved sorption capacities of ∼31 mg g⁻¹ and ∼19 mg g⁻¹ until the breakthrough point for MO and RB, respectively. The findings reveal that TiO₂-modified Al₂O₃ microspheres were rapidly prepared by spray pyrolysis, and they effectively treated organic dyes in water in batch and continuous flow removal processes.