Issue 25, 2023, Issue in Progress

Stabilization of Pd NPs over the surface of β-cyclodextrin incorporated UiO-66-NH2 for the C–C coupling reaction

Abstract

Here, we prepared UiO-66-NH2 and employed a post-synthesis modification method for its functionalization with a β-cyclodextrin (β-CD) organic compound. The resulting composite was employed as a support for the heterogenization of the Pd NPs. Various techniques, including FT-IR, XRD, SEM, TEM, EDS, and elemental mapping, were used to characterize UiO-66-NH2@β-CD/PdNPs, indicating its successful preparation. Three C–C coupling reactions, including the Suzuki, Heck, and Sonogashira coupling reactions, were promoted using the produced catalyst. As a result of the PSM, the proposed catalyst displays improved catalytic performance. In addition, the suggested catalyst was highly recyclable up to 6 times.

Graphical abstract: Stabilization of Pd NPs over the surface of β-cyclodextrin incorporated UiO-66-NH2 for the C–C coupling reaction

Supplementary files

Article information

Article type
Paper
Submitted
31 Dec 2022
Accepted
01 Mar 2023
First published
07 Jun 2023
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2023,13, 17143-17154

Stabilization of Pd NPs over the surface of β-cyclodextrin incorporated UiO-66-NH2 for the C–C coupling reaction

L. Mohammadi, R. Taghavi, M. Hosseinifard, M. R. Vaezi and S. Rostamnia, RSC Adv., 2023, 13, 17143 DOI: 10.1039/D2RA08347G

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