Catalytic degradation of azo dyes by bimetallic nanoparticles loaded in smart polymer microgels

Abstract

The contamination of water by azo dyes is increasing rapidly due to their waste use in textile industries. These dyes are very toxic for living things. Therefore, it is very important to remove these dyes from water. Various materials are reported for this purpose. Here, the most effective system of bimetallic nanoparticles in smart polymer microgels was prepared. The microgel system of N-isopropylmethacrylamide (NMA) (monomer) and methacrylic acid (MAa) (comonomer) was synthesized by a free radical precipitation polymerization method and then bimetallic (Ag/Ni) nanoparticles were encapsulated into the P(NMA-MAa) microgels by in situ reduction of both silver and nickel salts by NaBH₄ (reductant) after insertion of both (Ag⁺/Ni²⁺) ions. The P(NMA-MAa) microgels and Ag/Ni-P(NMA-MAa) hybrid microgels were characterized with FTIR, UV-vis, TGA, XRD, DLS, EDX, and STEM. The pH and temperature responsive behavior of Ag/Ni-P(NMA-MAa) was also evaluated. The catalytic efficiency of Ag/Ni-P(NMA-MAa) was assessed for degradation of methyl orange (MOr), congo red (CRe), eriochrome black T (EBlT) and methyl red (MRe) dyes under various conditions in aqueous medium. The apparent rate constant (k₀) value for MOr, CRe, EBlT and MRe was found to be 0.925 min⁻¹, 0.486 min⁻¹, 0.540 min⁻¹ and 0.525 min⁻¹ respectively. The Ag/Ni-P(NMA-MAa) was found to be an excellent recyclable catalyst.