High strontium adsorption performance of layered zirconium phosphate intercalated with a crown ether

Abstract

Effective removal of strontium isotopes in radioactive waste streams has important implications for the environment and the sustainable development of nuclear energy. In this work, a zirconium phosphate/18-crown-ether-6 (ZrP/18C6) composite was prepared using the intercalation method by loading crown ether into zirconium phosphate. The composite was structurally and morphologically characterized by XRD, FT-IR, XPS, and SEM. The adsorption experiments of Sr²⁺ onto the ZrP/18C6 composite were conducted as a function of temperature, pH, Sr²⁺ concentration and competing ions. The results indicate ZrP/18C6 can adsorb 98.6% of Sr²⁺ within 30 minutes at an Sr²⁺ concentration of 100 mg L⁻¹ and maintain a high removal rate with a distribution coefficient of 7 × 10⁵ mL g⁻¹ when Sr²⁺ is at a low level of 4.28 mg L⁻¹. The ZrP/18C6 composite reached a maximum adsorption capacity of 195.74 mg g⁻¹ at an Sr²⁺ concentration of 380 mg L⁻¹, which is significantly higher than the 43.03 mg g⁻¹ of α-ZrP. The adsorption performance of Sr²⁺ onto ZrP/18C6 is not significantly affected by temperature, pH and competing ions. Furthermore, the adsorption kinetics and thermodynamics were analyzed based on the adsorption data obtained in the present work. It is shown that the adsorption of Sr²⁺ onto ZrP/18C6 follows the pseudo-second-order model and the Langmuir monolayer model, respectively. Additionally, the adsorption mechanism of Sr²⁺ by ZrP/18C6 is discussed.