In situ synthesis of a Bi2O3 quantum dot decorated BiOCl heterojunction with superior photocatalytic capability for organic dye and antibiotic removal

Abstract

As a decoration method, coupling a photocatalyst with semiconductor quantum dots has been proven to be an efficient strategy for enhanced photocatalytic performance. Herein, a novel BiOCl nanosheet decorated with Bi₂O₃ quantum dots (QDs) was first synthesized by a facile one-step in situ chemical deposition method at room temperature. The as-prepared materials were characterized by multiple means of analysis. The Bi₂O₃QDs with an average diameter of about 8.0 nm were uniformly embedded on the surface of BiOCl nanosheets. The obtained Bi₂O₃QDs/BiOCl exhibited significantly enhanced photocatalytic performance on the degradation of the rhodamine B and ciprofloxacin, which could be attributed to the band alignment, the photosensitization effect and the strong coupling between Bi₂O₃ and BiOCl. In addition, the dye photosensitization effect was demonstrated by the monochromatic photodegradation experiments. The radical trapping experiments and the ESR testing demonstrated the type II charge transfer route of the heterojunction. Finally, a reasonable photocatalytic mechanism based on the relative band positions was discussed to illustrate the photoreaction process. These findings provide a good choice for the design and potential application of BiOCl-based photocatalysts in water remediation.