Synthesis and properties of SiO2/SiO2@Ag two-phase STFs

Abstract

Soft body armor with a strain-sensing function using conductive shear thickening fluids (STFs) has gradually gained research interest. In this study, conductive SiO₂@Ag core–shell microspheres were synthesized and the influence of process parameters on their properties was evaluated. Subsequently, SiO₂ and SiO₂@Ag were used as dispersed phases to prepare two-phase STFs, the effect of the core–shell microspheres' proportion on the rheological properties of the STFs was investigated, and its mechanism was discussed. The results indicated that SiO₂@Ag core–shell microspheres were coated with elemental silver and when the concentration of sodium hydroxide and glucose were 0.07 and 0.09 mol L⁻¹, respectively, the coating surface was the most uniform and compact, and the conductivity reached the minimum value of 0.56 Ω cm. The two-phase STFs exhibited good and reversible shear thickening behaviors and the critical shear rate decreased with increasing core–shell microsphere concentration. Additionally, when the mass fraction of SiO₂ and SiO₂@Ag core–shell microspheres was 45% and 20%, respectively, the thickening rate was 325%, and the resistance of two-phase STFs decreased simultaneously with the emergence of shear thickening that reached the lowest value of 795.16 kΩ. This study provides a novel strategy for synthesizing conductive STFs for strain-sensing flexible stab-resistant composites.