Issue 2, 2023

Magnetically separable triazine-based Cu(ii)–vitamin B5 complex in nitromethane toward efficient heterogeneous cyanation reaction of aryl halides

Abstract

In the current study, a highly efficient heterogeneous copper catalyst has been developed by supporting copper acetate on a magnetically separable triazine–vitamin B5 system. After the successful characterization of the prepared nanoparticles by various techniques such as FT-IR, FE-SEM, EDX/MAP, XRD, TEM, TGA, VSM, and ICP-OES, the catalytic efficiency of them were evaluated in the cyanation reaction of aryl halides in the presence of nitromethane as a non-toxic and cost-effective cyanation source. The cyanation products were obtained in desirable yields. Notably, the magnetic nanocatalyst can be easily recovered and reused at least five times without a significant decrease in its performance.

Graphical abstract: Magnetically separable triazine-based Cu(ii)–vitamin B5 complex in nitromethane toward efficient heterogeneous cyanation reaction of aryl halides

Supplementary files

Article information

Article type
Paper
Submitted
27 Sep 2022
Accepted
20 Dec 2022
First published
05 Jan 2023
This article is Open Access
Creative Commons BY license

RSC Adv., 2023,13, 1412-1421

Magnetically separable triazine-based Cu(II)–vitamin B5 complex in nitromethane toward efficient heterogeneous cyanation reaction of aryl halides

F. Karimi, M. Jadidi Nejad, A. Salamatmanesh and A. Heydari, RSC Adv., 2023, 13, 1412 DOI: 10.1039/D2RA06104J

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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