A new compound Na5Mn4(PO4)4F4·2H2O with a rarely mixed valence spin chain showing multiple magnetic transitions

Qi Luo; Ningxia Li; Zhiying Zhao; Meiyan Cui; Zhangzhen He

doi:10.1039/D3QI01389H

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A new compound Na₅Mn₄(PO₄)₄F₄·2H₂O with a rarely mixed valence spin chain showing multiple magnetic transitions†

Qi Luo,^ab Ningxia Li,^a Zhiying Zhao,

^a Meiyan Cui

^a and Zhangzhen He

*^a

Author affiliations

* Corresponding authors

^a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China
E-mail: hezz@fjirsm.ac.cn, hcz1988@hotmail.com

^b College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China

Abstract

A new compound Na₅Mn₄(PO₄)₄F₄·2H₂O was successfully obtained, featuring a typical channel structure composed of rarely mixed valence Mn²⁺/Mn³⁺ spin chains and PO₄ tetrahedra, where H₂O molecules are located inside the channels. Magnetic measurements show that this compound possesses successive multiple magnetic transitions at low temperature.

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Article information

DOI: https://doi.org/10.1039/D3QI01389H
Article type: Research Article
Submitted: 20 Jul 2023
Accepted: 09 Sep 2023
First published: 11 Sep 2023

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Inorg. Chem. Front., 2023,10, 6303-6307

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A new compound Na₅Mn₄(PO₄)₄F₄·2H₂O with a rarely mixed valence spin chain showing multiple magnetic transitions

Q. Luo, N. Li, Z. Zhao, M. Cui and Z. He, Inorg. Chem. Front., 2023, 10, 6303 DOI: 10.1039/D3QI01389H

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