Rb3B5O8F2 and K0.6Rb2.4B5O8F2: two new deep-ultraviolet transparent nonlinear optical fluorooxoborates designed by cation regulation

Ruonan Zhang; Bingliang Cheng; Xuping Wang; Rong Yang; Zhihua Yang; Shujuan Han; Shilie Pan

doi:10.1039/D2QI01466A

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Rb₃B₅O₈F₂ and K_0.6Rb_2.4B₅O₈F₂: two new deep-ultraviolet transparent nonlinear optical fluorooxoborates designed by cation regulation†

Ruonan Zhang,‡^ab Bingliang Cheng,‡^ab Xuping Wang,

^a Rong Yang,^ab Zhihua Yang,

^a Shujuan Han

*^a and Shilie Pan

*^a

Author affiliations

* Corresponding authors

^a Research Center for Crystal Materials; CAS Key Laboratory of Functional Materials and Devices for Special Environments; Xinjiang Technical Institute of Physics and Chemistry, CAS, 40-1 South Beijing Road, Urumqi 830011, China
E-mail: hansj@ms.xjb.ac.cn, slpan@ms.xjb.ac.cn

^b Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

Two new fluorooxoborates, Rb₃B₅O₈F₂ and K_0.6Rb_2.4B₅O₈F₂, were successfully obtained by cation regulation. Both of them crystallize in a non-centrosymmetric space group P2₁. The structural evolution from Li₂Na_0.9K_0.1B₅O₈F₂ to Rb₃B₅O₈F₂, as well as the structural comparison between RbB₅O₈ and Rb₃B₅O₈F₂, is discussed in detail. The linear optical and nonlinear optical properties were measured. Furthermore, the structure–property relationships of the alkali metal fluorooxoborates were determined by theoretical calculations.

This article is part of the themed collections: 2023 Inorganic Chemistry Frontiers HOT articles and FOCUS: Frontiers in Boron Chemistry

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Article information

DOI: https://doi.org/10.1039/D2QI01466A
Article type: Research Article
Submitted: 08 Jul 2022
Accepted: 05 Dec 2022
First published: 07 Dec 2022

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Inorg. Chem. Front., 2023,10, 787-792

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Rb₃B₅O₈F₂ and K_0.6Rb_2.4B₅O₈F₂: two new deep-ultraviolet transparent nonlinear optical fluorooxoborates designed by cation regulation

R. Zhang, B. Cheng, X. Wang, R. Yang, Z. Yang, S. Han and S. Pan, Inorg. Chem. Front., 2023, 10, 787 DOI: 10.1039/D2QI01466A

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