Issue 23, 2023

Visible light-mediated three-component functionalization of olefins with sulfoxyimidoylsulfonium salt for the synthesis of β-amino alcohols and amino ethers

Abstract

A new strategy involving three-component functionalization of olefins with sulfoxyimidoylsulfonium salt and a nucleophilic reagent for the synthesis of β-amino alcohols and β-amino ethers by photoredox catalysis was developed. The sulfoxyimidoylsulfonium salt is important and serves as the N-centred radical precursor. β-Amino alcohols and β-amino ethers bearing various functional groups are synthesized in good yields under mild conditions. Furthermore, the advantages of this strategy are greater safety, no additives, and easy to obtain raw materials.

Graphical abstract: Visible light-mediated three-component functionalization of olefins with sulfoxyimidoylsulfonium salt for the synthesis of β-amino alcohols and amino ethers

Supplementary files

Article information

Article type
Paper
Submitted
16 Apr 2023
Accepted
26 May 2023
First published
01 Jun 2023

Org. Biomol. Chem., 2023,21, 4909-4912

Visible light-mediated three-component functionalization of olefins with sulfoxyimidoylsulfonium salt for the synthesis of β-amino alcohols and amino ethers

W. Xie, L. Zhao, X. Fu, R. Zhang, X. Hao, C. Duan and Y. Li, Org. Biomol. Chem., 2023, 21, 4909 DOI: 10.1039/D3OB00585B

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