Issue 23, 2023

Self-limiting stoichiometry in SnSe thin films

Abstract

Unique functionalities can arise when 2D materials are scaled down near the monolayer limit. However, in 2D materials with strong van der Waals bonds between layers, such as SnSe, maintaining stoichiometry while limiting vertical growth is difficult. Here, we describe how self-limiting stoichiometry can promote the growth of SnSe thin films deposited by molecular beam epitaxy. The Pnma phase of SnSe was stabilized over a broad range of Sn : Se flux ratios from 1 : 1 to 1 : 5. Changing the flux ratio does not affect the film stoichiometry, but influences the predominant crystallographic orientation. ReaxFF molecular dynamics (MD) simulation demonstrates that, while a mixture of Sn/Se stoichiometries forms initially, SnSe stabilizes as the cluster size evolves. The MD results further show that the excess selenium coalesces into Se clusters that weakly interact with the surface of the SnSe particles, leading to the limited stoichiometric change. Raman spectroscopy corroborates this model showing the initial formation of SnSe2 transitioning into SnSe as experimental film growth progresses. Transmission electron microscopy measurements taken on films deposited with growth rates above 0.25 Å s−1 show a thin layer of SnSe2 that disrupts the crystallographic orientation of the SnSe films. Therefore, using the conditions for self-limiting SnSe growth while avoiding the formation of SnSe2 was found to increase the lateral scale of the SnSe layers. Overall, self-limiting stoichiometry provides a promising avenue for maintaining growth of large lateral-scale SnSe for device fabrication.

Graphical abstract: Self-limiting stoichiometry in SnSe thin films

Associated articles

Supplementary files

Article information

Article type
Paper
Submitted
10 Feb 2023
Accepted
07 May 2023
First published
05 Jun 2023
This article is Open Access
Creative Commons BY license

Nanoscale, 2023,15, 9973-9984

Self-limiting stoichiometry in SnSe thin films

J. R. Chin, M. B. Frye, D. S. Liu, M. Hilse, I. C. Graham, J. Shallenberger, K. Wang, R. Engel-Herbert, M. Wang, Y. K. Shin, N. Nayir, A. C. T. van Duin and L. M. Garten, Nanoscale, 2023, 15, 9973 DOI: 10.1039/D3NR00645J

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements