Galvanic replacement-induced introduction of a heteroligand into bimetallic and trimetallic nanoclusters

Abstract

Heteroleptic 8-electron silver-rich alloy nanoclusters, [Au@Au₄Ag₁₂(dtp)₇(PPh₃)₄]²⁺ (1) and [Pt@Au₄Ag₁₁(dtp)₇(PPh₃)₄] (2), were successfully synthesized via a galvanic replacement reaction of 1,1-dithiolate-protected M@Ag₂₀ (M = Au and Pt) nanoclusters with Au(I)-phosphine salts, leading to the alteration of the cluster nuclearity and geometry of shell skeletons but retaining the same 8-electron count.