Doping and pretreatment optimized the adsorption of *OCHO on bismuth for the electrocatalytic reduction of CO2 to formate

Abstract

Electrocatalytic reduction of CO₂ to formate is considered as a promising method to achieve carbon neutrality, and the introduction of heteroatoms is an effective strategy to improve the catalytic activity and selectivity of catalysts. However, the structural reconstruction behavior of catalysts driven by voltage is usually ignored. Therefore, we used Cu/Bi₂S₃ as a model to reveal the dynamic reduction process in different atmospheric environments. The catalyst showed an outstanding faradaic efficiency of 94% for formate and a long-term stability of 100 h, and exhibited a high current density of 280 mA cm⁻² in a flow cell. The experimental results and theoretical calculations show that the introduction of copper enhances the adsorption of CO₂, accelerates the charge transfer and reduces the formation barrier of *OCHO, thus promoting the formation of formate. This work draws attention to the effects of saturated gases in the electrolyte during structural evolution and provides a possibility for designing catalysts with high catalytic activity.