Aquacobalamin reacts with m-chloroperoxybenzoic acid (MCPBA) to form a Co(III)-peroxo complex, as supported by UV-vis, NMR and resonance Raman spectra complemented by mass spectra and density functional calculations. At high MCPBA concentrations, degradation of cobalamin is observed as previously described.
M. Lehene, C. Zăgrean-Tuza, N. Hădade, A. Aghion, R. Şeptelean, S. D. Iancu, A. M.V. Brânzanic and R. Silaghi-Dumitrescu, New J. Chem., 2023, 47, 18178 DOI: 10.1039/D3NJ03307D
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