A new ligand-regulated strategy of highly mesoporous metal–organic frameworks assembled in ionic liquid/ethanol solvent

Xiaoxue Ma; Pan Ren; Donglu Fu; Xinchen Kang; Minghua Jing; Xinxin Sang; Dawei Fang; Zongren Song

doi:10.1039/D3NJ01793A

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A new ligand-regulated strategy of highly mesoporous metal–organic frameworks assembled in ionic liquid/ethanol solvent†

Xiaoxue Ma,^a Pan Ren,^a Donglu Fu,^a Xinchen Kang,

^b Minghua Jing,^a Xinxin Sang,

^c Dawei Fang

*^a and Zongren Song

*^a

Author affiliations

* Corresponding authors

^a Institute of Rare and Scattered Elements, College of Chemistry, Liaoning University, Shenyang, Liaoning 110036, China
E-mail: dwfang@lnu.edu.cn, zongrensong@lnu.edu.cn

^b Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

^c The Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, Jiangnan University, Wuxi 214122, China

Abstract

Hierarchical porous metal–organic framework catalysts were synthesized by ligand regulation in an ionic liquid/ethanol system for the first time. The porosity and morphology could be tuned by the mass fraction of ionic liquid/ethanol and ligand. The hierarchical porous metal–organic framework catalysts exhibited very high activity and stability for the oxidation of alcohol.

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Article information

DOI: https://doi.org/10.1039/D3NJ01793A
Article type: Communication
Submitted: 19 Apr 2023
Accepted: 08 May 2023
First published: 06 Jun 2023

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New J. Chem., 2023,47, 11755-11759

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A new ligand-regulated strategy of highly mesoporous metal–organic frameworks assembled in ionic liquid/ethanol solvent

X. Ma, P. Ren, D. Fu, X. Kang, M. Jing, X. Sang, D. Fang and Z. Song, New J. Chem., 2023, 47, 11755 DOI: 10.1039/D3NJ01793A

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New Journal of Chemistry

A new ligand-regulated strategy of highly mesoporous metal–organic frameworks assembled in ionic liquid/ethanol solvent†

Abstract

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A new ligand-regulated strategy of highly mesoporous metal–organic frameworks assembled in ionic liquid/ethanol solvent

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