Ligand-directed structure evolution from a titanium-oxo cluster to coordination capsule and one-dimensional coordination polymer based on {Ti3O} units

Min Meng; Lingrong Liao; Qi Zheng; Weimin Xuan

doi:10.1039/D3NJ01172K

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Ligand-directed structure evolution from a titanium-oxo cluster to coordination capsule and one-dimensional coordination polymer based on {Ti₃O} units†

Min Meng,^a Lingrong Liao,^b Qi Zheng

*^b and Weimin Xuan

*^a

Author affiliations

* Corresponding authors

^a State Key Laboratory for Modification of Chemical Fibers and Polymer Materials and College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, P. R. China
E-mail: weiminxuan@dhu.edu.cn

^b State Key Laboratory for Modification of Chemical Fibers and Polymer Materials & College of Materials Science and Engineering, Donghua University, Shanghai 201620, P. R. China
E-mail: qi.zheng@dhu.edu.cn

Abstract

By modulating the geometry and size of the ligand and using phosphite as a bridging linker, {Ti₃(μ₃-O)} can be assembled into a discrete {Ti₆} cluster, coordination capsule {Ti₁₈Cu₃} and one-dimensional coordination polymer {Ti₆}_n.

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Article information

DOI: https://doi.org/10.1039/D3NJ01172K
Article type: Paper
Submitted: 12 Mar 2023
Accepted: 08 May 2023
First published: 11 May 2023

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New J. Chem., 2023,47, 11312-11317

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Ligand-directed structure evolution from a titanium-oxo cluster to coordination capsule and one-dimensional coordination polymer based on {Ti₃O} units

M. Meng, L. Liao, Q. Zheng and W. Xuan, New J. Chem., 2023, 47, 11312 DOI: 10.1039/D3NJ01172K

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