Kilogram-scale fabrication of TiO2 nanoparticles modified with carbon dots with enhanced visible-light photocatalytic activity

Abstract

Incorrect discharge of dye wastewater will cause environment pollution and be very harmful to human health. Visible-light photocatalysis over large-scale synthesized semiconductor materials can become one of the feasible solutions for the practical application of purifying dye wastewater. As a new candidate, carbon dots (CDs) with unique fluorescence were fabricated on a tens of grams scale and then further applied to the kilogram-scale synthesis of a CDs/TiO₂ composite by one-step heat treatment. Compared with single TiO₂ nanoparticles (NPs), the CDs/TiO₂ composite with a large specific surface area exhibits enhanced photo-degradation performance for methyl orange (MO). This phenomenon can be attributed to the loading of CDs in the TiO₂ NPs, which is conducive to broadening the light absorption spectrum and improving absorption intensity, narrowing the band gap, charge carrier trapping, up-converting properties, and charge separation. The kilogram-scale synthesis of the CDs/TiO₂ photocatalyst does not affect the morphology, structure, optical properties and photocatalytic performance of the composite, which opens up a new avenue to construct elaborate heterostructures for enhanced photocatalytic performance using visible light as the light source.