A Dy-based single ion magnet in a SrLaGaO4 matrix: enhanced parameters in an expanded crystal lattice†
Abstract
Dy3+ doped SrLaGaO4 exhibits unusually slow relaxation of magnetization determined by two widely separated excited Kramers doublets with a second remagnetization energy barrier of 223 cm−1. This value considerably exceeds that for analogous Ca(Y,Dy)AlO4 in spite of the apparently enlarged Dy3+ coordination sphere.